@article {46166,
	title = {Aryne Sommelet-Hauser rearrangement},
	journal = {Chemical Communications},
	volume = {55},
	year = {2019},
	month = {MAR},
	pages = {3004-3007},
	type = {Article},
	abstract = {<p>An aryne induced transition-metal-free and mild Sommelet-Hauser rearrangement of tertiary benzylamines for the synthesis of -aryl amino acid derivatives in moderate to good yields is presented. Unlike the conventional Sommelet-Hauser rearrangement of ammonium salts, the methodology developed herein requires neither harsh conditions nor strong bases. Moreover, a temperature dependent switchable selectivity for the Sommelet-Hauser and Stevens [1,2] rearrangements has been observed.</p>
},
	issn = {1359-7345},
	doi = {10.1039/c9cc00629j},
	author = {Roy, Tony and Gaykar, Rahul N. and Bhattacharjee, Subrata and Biju, Akkattu T.}
}
