@article {45518,
	title = {Gold-catalyzed 1,2-oxyalkynylation of N-Allenamides with ethylnylbenziodoxolones},
	journal = {Organic Letters},
	volume = {21},
	year = {2019},
	month = {JAN},
	pages = {180-184},
	type = {Article},
	abstract = {<p>A gold-catalyzed 1,2-oxyalkynylation of N-allenamides with ethylnylbenziodoxolones (EBXs) has been achieved for the first time. The reaction, which follows a redox-neutral Au(I)/Au(III) catalytic pathway, was enabled in an attempt to exhaust the EBX reagents atom-economically by putting the nucleophilic carboxylate part of EBXs to appropriate use. This constitutes the first example for gold-catalyzed beta-alkynylation of N-allenamides to construct highly valuable 1,3-enynes. The potential of the sequence is further documented by some follow-up transformations.</p>},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.8b03651},
	author = {Banerjee, Somsuvra and Senthilkumar, Beeran and Patil, Nitin T.}
}
