@article {43668,
	title = {Reductive activation of O-2 by a bioinspired Fe complex for catalytic epoxidation reactions},
	journal = {Chemical Communications},
	volume = {53},
	year = {2017},
	month = {MAY},
	pages = {5914-5917},
	type = {Article},
	abstract = {Aerobic epoxidation of olefins catalyzed by iron complexes without the use of a sacrificial coreductant is unknown. We report the reductive activation of O-2 by a bioinspired [(bTAML)Fe-III(H2O)](-) (1) complex to catalyze the epoxidation of alkenes with TONs of up to 80. Spectroscopic and kinetic evidence indicates the involvement of FeV(O) as the active oxidant during the reaction.},
	doi = {10.1039/c7cc00933j},
	author = {Singh, Kundan K. and Sen Gupta, Sayam}
}
