@article {43638,
	title = {Electrocatalytic water oxidation by a molecular cobalt complex through a high valent cobalt oxo intermediate},
	journal = {Chemical Communications},
	volume = {52},
	year = {2016},
	month = {AUG},
	pages = {11787-11790},
	abstract = {Biuret-modified tetraamidomacrocyclic cobalt complex [Co-III-bTAML]- is shown to catalyze electrochemical water oxidation at basic pH leading to the formation of O-2. Electrochemical and spectroscopic studies indicate a high valent cobalt oxo intermediate isoelectronic to Co-V(O) as the active oxidant. The kinetic isotope effect of 8.63 indicates an atom proton transfer mechanism.},
	doi = {10.1039/c6cc05773j},
	author = {Das, Debasree and Pattanayak, Santanu and Singh, Kundan K. and Garai, Bikash and Sen Gupta, Sayam}
}
