@article {42750,
	title = {O-2-Naphthyl diphenylthiophosphinate},
	journal = {Acta Crystallographica Section E-Crystallographic Communications},
	volume = {63},
	year = {2007},
	month = {DEC},
	pages = {4644},
	type = {Article},
	abstract = {<p>The mol-ecule of the title compound, C10H7OP(S)(C6H5)2 or C22H17OPS, exhibits distorted tetra-hedral geometry about the P atom. The P=S bond of 1.9355 (4) {\r A} is shorter than that found in Ph3P=S [1.950 (3) {\r A}] because the replacement of one carbon on phospho-rus by oxygen increases the effective electronegativity of the P atom, thereby enhancing pπ{\textendash}dπ back-donation from a lone-pair orbital of the S atom.</p>},
	doi = {10.1107/S1600536807056127},
	author = {Mague, Joel T. and Punji, Benudhar and Ganesamoorthy, Chelladurai and Balakrishna, Maravanji S.}
}
