@article {42730,
	title = {Hydrophosphonylation of activated alkenes and alkynes via fluoride ion activation in ionic liquid medium},
	journal = {Tetrahedron},
	volume = {65},
	year = {2009},
	month = {JUL},
	pages = {7603{\textendash}7610},
	abstract = {<p>A simple transition metal-free hydro/hydrothiophosphonylation of Baylis{\textendash}Hillman adducts, substituted allyl bromides, allenylphosphonates and alkynes, promoted by fluoride ion in ionic liquid, is described. Clear-cut evidence for fluoride activation of the phosphite via pentacoordinate phosphorus is provided for the first time. Also, in a comparative reaction, the product obtained was different from that from the palladium catalyzed one. Structures of key products are proven by X-ray crystallography.</p>},
	doi = {10.1016/j.tet.2009.06.096},
	author = {Balaraman, Ekambaram and Srinivas, Venu and Swamy, K. C. Kumara}
}
