@article {42417,
	title = {Aryne [2,3] stevens rearrangement},
	journal = {Organic Letters},
	volume = {18},
	year = {2016},
	month = {OCT},
	pages = {5428-5431},
	abstract = {<p>Arynes are employed in the transition-metal-free and mild [2,3] Stevens rearrangement of tertiary allylic amines for the synthesis of functionalized homoallylic amines in moderate to good yield with a broad substrate scope. The key nitrogen ylide intermediate was generated by the <i>N</i>-arylation of allyl amines using arynes. Moreover, the reaction of chiral allyl amines with arynes resulted in the enantiospecific synthesis of homoallylic amines. In addition, preliminary studies on the [1,2] Stevens rearrangement is also presented.</p>},
	doi = {10.1021/acs.orglett.6b02809},
	author = {Roy, Tony and Thangaraj, Manikandan and Kaicharla, Trinadh and Kamath, Rupa V. and Gonnade, Rajesh G. and Biju, Akkattu T.}
}
