@article { ISI:000239671800023,
	title = {Cobalt-containing hexagonal mesoporous molecular sieves (Co-HMS): Synthesis, characterization and catalytic activity in the oxidation reaction of ethylbenzene},
	journal = {Journal of Molecular Catalysis A-Chemical},
	volume = {255},
	number = {1-2},
	year = {2006},
	month = {AUG},
	pages = {123-130},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>Cobalt-containing hexagonal mesoporous materials (Co-HMS and Co/HMS) with different cobalt content were synthesized for the first time by direct hydrothermal and post-synthesis (grafting) method. The materials were characterized in detail by X-ray diffraction, BET surface area, N-2 sorption isotherms, SEM, TEM, UV-vis and XPS techniques. Powder X-ray diffraction pattern, N2 adsorption-desorption analysis and TEM analysis show the presence of hexagonal mesoporous structure, having Type W isotherms and reveals the typical wormhole-like morphology. Spectroscopic techniques like UV-vis and XPS reveal cobalt in +2 oxidation state and tetrahedrally coordinated. Liquid phase oxidation of ethylbenzene using TBHP (70 wt\%) as an oxidant shows that the catalysts are highly active, under solvent free conditions as well as under lower cobalt concentrations. Leaching studies performed by hot filtration experiments show that the cobalt catalysts prepared by hydrothermal methods are stable, while the grafted catalysts show the leaching of cobalt under the reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.</p>},
	keywords = {Co-HMS, ethylbenzene, HMS, hydrothermal, Oxidation},
	issn = {1381-1169},
	doi = {10.1016/j.molcata.2006.03.072},
	author = {Bhoware, Shrikant S. and Shylesh, S. and Kamble, K. R. and Singh, A. P.}
}
