@article { ISI:000249501700020,
	title = {Homogeneous nucleation temperatures in aqueous mixed salt solutions},
	journal = {Journal of Physical Chemistry B},
	volume = {111},
	number = {37},
	year = {2007},
	month = {SEP},
	pages = {10985-10991},
	publisher = {AMER CHEMICAL SOC},
	type = {Article},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>This is the first report on the measurement of homogeneous nucleation temperature, T-H, in the presence of aqueous mixed salt systems of varying compositions and ionic strengths. The T-H,T-m (T-H value in aqueous mixed salt system) data for these systems have been analyzed in terms of a simple empirical equation. The T-H.m. values in simple aqueous mixed salts like NaCl-KCl can be approximated by linear summation of the products of ionic strength fraction and the T-H values of pure salt solutions at the same ionic strength as that of the mixture. The empirical parameter, q(0), indicating ionic interaction is related to the viscosity B-coefficients. The T-H.m data, though correlated on the basis of the B-coefficients also depends upon the mixing of two ions of like charges. Further, a linear correlation exists between the q(0) parameter and self-diffusion coefficient, D-0, of the ionic solute. The q(0) parameter is also well correlated with the rotational correlation time, T-c(h)/T-c(0) of the ionic species involved in the mixtures. It is possible to compute T-H,T-m for the salt mixtures with no common ions from the knowledge of the T-H,T-m values of the salt mixtures with common ions.</p>},
	issn = {1520-6106},
	doi = {10.1021/jp073846z},
	author = {Kumar, Anil}
}
