@article { ISI:000257533800025,
	title = {Synthesis, structure and reactivity of azosalophen complexes of palladium},
	journal = {Polyhedron},
	volume = {27},
	number = {9-10},
	year = {2008},
	month = {JUN},
	pages = {2209-2215},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	type = {Article},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>The ligands 2-(arylazo)-1-N-salicylidene phenylamine, H(2)L(sal), (where H represents the dissociable protons upon complexation) afford stable orthopalladated complexes, [(L(sal))Pd], upon treatment with Na(2)[PdCl(4)]. The dinegative anionic (L(sal))(2-) ligands bind Pd(II) in a tetradentate (C, N, N, O) fashion with a distorted square planar geometry. The newly synthesized palladium complexes underwent oxygen insertion into the Pd-C bond with mCPBA (m-chloroperbenzoic acid) or TBHP (terbutylhydroperoxide)/[VO(acac)(2)] leading to the formation of stable azosalophen complexes of Pd(II) with the (O, N, N, O) coordination mode of the oxygenated ligand. (C) 2008 Elsevier Ltd. All rights reserved.</p>},
	keywords = {2-(arylazo)-1-N-salicylidene phenylamine, azosalophen complex, orthopalladation, oxygen insertion},
	issn = {0277-5387},
	doi = {10.1016/j.poly.2008.03.028},
	author = {Pattanayak, Poulami and Pratihar, Jahar Lal and Patra, Debprasad and Puranik, Vedavati G. and Chattopadhyay, Surajit}
}
