@article { ISI:000289926300019,
	title = {Effect of blend composition and organoclay loading on the nanocomposite structure and properties of miscible poly(methyl methacrylate)/poly(styrene-co-acrylonitrile) blends},
	journal = {Polymer Engineering and Science},
	volume = {51},
	number = {5},
	year = {2011},
	month = {MAY},
	pages = {979-991},
	publisher = {WILEY-BLACKWELL},
	address = {COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA},
	abstract = {<p>Organically-modified montmorillonite clay nanocomposites of poly(styrene-co-acrylonitrile) (SAN), poly(methyl methacrylate) (PMMA) and SAN/PMMA miscible blend are investigated. Structure characteristics at the nanoscale and microscale and thermal and tensile properties are studied as a function of polymer blend composition and filler loading fraction. Blend miscibility and T(g) are unaffected by up to 10\% by wt. organoclay. Thermal degradation stability increases with SAN content and exhibits an optimum value of clay loading. Stiffness shows significant improvement. Tensile strength and elongation-at-break suffer as a result of nanocomposite formation. Modulus shows a maximum enhancement of 57\% (5 +/- 0.06 GPa at 10 wt\% filler, 20/80 SAN/PMMA) and varies linearly with clay fraction for all compositions of matrix phase. Predictions of Halpin-Tsai composite model are in excellent agreement with the experimental behavior over full range of polymer blend composition. Fundamental aspects of a polymer blend-clay nanocomposite are clarified, such as lack of additional synergy between clay platelets and matrix, and tensile ductility reduction, compared with polymer-clay system. POLYM. ENG. SCI., 51:979-991, 2011. (C) 2011 Society of Plastics Engineers</p>},
	issn = {0032-3888},
	doi = {10.1002/pen.21887},
	author = {Tiwari, Rajkiran R. and Natarajan, Upendra}
}
