@article { ISI:000329960500033,
	title = {Unexpected observations during the total synthesis of calothrixin B-sodium methoxide as a source of hydride},
	journal = {Tetrahedron Letters},
	volume = {55},
	number = {1},
	year = {2014},
	month = {JAN},
	pages = {155-162},
	publisher = {PERGAMON-ELSEVIER SCIENCE LTD},
	address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND},
	abstract = {<p>During the total synthesis of calothrixin B, various novel and unexpected results were noticed such as cleavage of C-N bond in imine using sodium cyanoborohydride, sodium methoxide as a hydride source for reduction, deformylation in the presence of bromine, and deacylation using ceric ammonium nitrate (CAN). A detailed mechanism has been proposed for the unexpected results and a few of them are generalized. Temperature dependent NMR studies have been carried out for confirmation of the structure of one of the intermediates in the synthetic sequence. (C) 2013 Elsevier Ltd. All rights reserved.</p>},
	keywords = {Azoxybenzene, Calothrixin B, reduction, Sodium cyanoborohydride, Sodium methoxide},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2013.10.140},
	author = {Bhosale, Shrikar M. and Momin, Aadil A. and Kunjir, Shrikant and Rajamohanan, P. R. and Kusurkar, Radhika S.}
}
