@article { ISI:000338980500002,
	title = {Formation of a room temperature stable Fe-V(O) complex: reactivity toward unactivated C-H bonds},
	journal = {Journal of American Chemical Society},
	volume = {136},
	number = {27},
	year = {2014},
	month = {JUL},
	pages = {9524-9527},
	publisher = {AMER CHEMICAL SOC},
	type = {Article},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>An Fe-V(O) complex has been synthesized from equimolar solutions of (Et4N)(2)[Fe-III(Cl)(biuretamide)] and mCPBA in CH3CN at room temperature. The Fe-V(O) complex has been characterized by UV-vis, EPR, Mossbauer, and HRMS and shown to be capable of oxidizing a series of alkanes having C-H bond dissociation energies ranging from 99.3 kcal mol(-1) (cyclohexane) to 84.5 kcal mori (cumene). Linearity in the Bell-Evans-Polayni graph and the finding of a large kinetic isotope effect suggest that hydrogen abstraction is engaged the rate-determining step.</p>},
	issn = {0002-7863},
	doi = {10.1021/ja412537m},
	author = {Ghosh, Munmun and Singh, Kundan K. and Panda, Chakadola and Weitz, Andrew and Hendrich, Michael P. and Collins, Terrence J. and Dhar, Basab B. and Sen Gupta, Sayam}
}
