@article { ISI:000358395100008,
	title = {Role of interfacial tension of solvating diluents and hydrophilic-hydrophobic cross-linkers in hyper-cross-linked solid supports},
	journal = {Industrial \& Engineering Chemistry Research},
	volume = {54},
	number = {27},
	year = {2015},
	month = {JUL},
	pages = {6893-6901},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>The properties of a hyper-cross-linked solid support are the outcome Of the interfacial tension created by solvating/nonsolvating diluents, the hydrophilicity/hydrophobicity of the cross-linkers, and their concentrations. Interestingly, a More hydrophobic diluent and cross-linker as well as a higher concentration of cross-linker-containing copolymer revealed an increase In surface area. A high surface area and low cross-link density (CLD) polymer illustrated higher epoxy content. Importantly, maximum surface area (533 m(2)/g) Was obtained at high CLD; inversely, epoxy,content (1.83 mmol/g) was higher at low CLD polymer. Notably, greater rigidity of cross-linker and its higher concentration increased T-max and T-g; contrarily, greater flexibility of cross-linker and its concentration attenuated T-max and T-g. Thermal study demonstrated the thermostability (300 degrees C) and polymer safe temperature (220 degrees C). Indeed, a lower solubility parameter difference between polymer and swelling solvent produces a higher polymer-solvent interaction parameter, resulting in increased polymer swelling. Polymers with high surface area and low CLD demonstrated greater swelling behavior.</p>},
	issn = {0888-5885},
	doi = {10.1021/acs.iecr.5b01277},
	author = {Mane, Sachin and Ponrathnam, Surendra and Chavan, Nayaku}
}
