@article { ISI:000366878300071,
	title = {Biomimetic synthesis of phaitanthrin e involving a fragmentation of sp(3) carbon-carbon bond: synthesis and rearrangement of phaitanthrin D to phaitanthrin E},
	journal = {Organic Letters},
	volume = {17},
	number = {24},
	year = {2015},
	month = {DEC},
	pages = {6218-6221},
	publisher = {AMER CHEMICAL SOC},
	address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
	abstract = {<p>A biogenetic type total synthesis of alkaloids phaitanthrin D and phaitanthrin E has been described. The Csp(3)-Csp(3) bond cleavage with the release of several heteroatoms bearing unexpected leaving groups in intramolecular substitution reactions on an iminium double bond in the quinazolinones has been demonstrated using HMDS/ZnCl2 or NaHMDS. The mechanistic aspects have been supported by isolation and characterization of appropriate intermediates.</p>},
	issn = {1523-7060},
	doi = {10.1021/acs.orglett.5b03203},
	author = {Vaidya, Sagar D. and N. P. Argade}
}
