%0 Journal Article %J Inorganic Chemistry %D 2015 %T Coherent fusion of water array and protonated amine in a metal-sulfate-based coordination polymer for proton conduction %A Manna, Biplab %A Anothumakkool, Bihag %A Desai, Aamod V. %A Samanta, Partha %A Kurungot, Sreekumar %A Ghosh, Sujit K. %X

A new function of metal-sulfate-based co-ordination polymer (CP) for proton,conduction Was investigated through rational integration of a continuous water array and protonated amine in the coordination space of the CP. The H-bonded arrays of watet molecules along with nitrogen-rich aromatic cation (protonated melamine) facilitate proton conduction in the compound under humid conditions. Although several reports of metal-oxalate/phosphate-based CPs showing proton conduction are known, this is the first designed synthesis of a metal sulfate-based CP bearing-Water arrays functioning as a solid-state proton conductor:

%B Inorganic Chemistry %I AMER CHEMICAL SOC %C 1155 16TH ST, NW, WASHINGTON, DC 20036 USA %V 54 %P 5366-5371 %8 JUN %G eng %N 11 %3

Foreign

%4 4.82 %R 10.1021/acs.inorgchem.5b00416