TY - JOUR T1 - Enantiospecific formal synthesis of inthomycin C JF - Chemistry Select Y1 - 2016 A1 - Athawale, Paresh R. A1 - Kashinath, K. A1 - Reddy, D. Srinivasa AB -

An enantiospecific synthesis of Hatakeyama's intermediate enynol has been accomplished in both enantiomeric forms. As these intermediates can be converted to (3R)-inthomycin C and (3S)-inthomycin C through respective enynol intermediates using reported procedures, present effort may be regarded as formal synthesis of inthomycin C in both enantiomeric forms. Our synthesis highlights the use of pantolactone chiral pool and thus reconfirms the previously assigned absolute stereochemistry as 3R to the natural product inthomycin C.

VL - 1 IS - 3 U3 -

Foreign

U4 - 0.00 ER -