TY - JOUR T1 - Coherent fusion of water array and protonated amine in a metal-sulfate-based coordination polymer for proton conduction JF - Inorganic Chemistry Y1 - 2015 A1 - Manna, Biplab A1 - Anothumakkool, Bihag A1 - Desai, Aamod V. A1 - Samanta, Partha A1 - Kurungot, Sreekumar A1 - Ghosh, Sujit K. AB -

A new function of metal-sulfate-based co-ordination polymer (CP) for proton,conduction Was investigated through rational integration of a continuous water array and protonated amine in the coordination space of the CP. The H-bonded arrays of watet molecules along with nitrogen-rich aromatic cation (protonated melamine) facilitate proton conduction in the compound under humid conditions. Although several reports of metal-oxalate/phosphate-based CPs showing proton conduction are known, this is the first designed synthesis of a metal sulfate-based CP bearing-Water arrays functioning as a solid-state proton conductor:

PB - AMER CHEMICAL SOC CY - 1155 16TH ST, NW, WASHINGTON, DC 20036 USA VL - 54 IS - 11 U3 -

Foreign

U4 - 4.82 ER -