01256nas a2200145   4500008004100000245008900041210006900130260000800199490000700207520073300214100001700947700001800964700001800982856011001000       2020                        eng d00aRole of exposed crystal facets in the atmospheric pressure CO hydrogenation on Co3O40 aRole of exposed crystal facets in the atmospheric pressure CO hy  cJUL0 v233 a<p><span style="color: rgb(51, 51, 51); font-family: Roboto, Arial, sans-serif; font-size: 14px; font-style: normal; font-variant-ligatures: normal; font-variant-caps: normal; font-weight: 400;">Co3O4 nanostructures with different exposed planes are studied for atmospheric pressure CO hydrogenation. Existence of different facets is characterized by HR-TEM and found Co3O4 - NSP (nanospheres) expose (112) facet, NB (nanobelts) exhibit (110) plane and (100) is the dominant surface facet in NC (nanocubes). Different catalytic activity is demonstrated by the specific facet of Co3O4 catalysts. CO hydrogenation is facet dependent and the catalytic activity follows the order of Co3O4-NB &gt; Co3O4-NC &gt; Co3O4-NSP.</span></p>1 aJain, Preeti1 aGupta, Sharad1 aVinod, C., P.  uhttp://library.ncl.res.in/content/role-exposed-crystal-facets-atmospheric-pressure-co-hydrogenation-co3o401587nas a2200229   4500008004100000022001400041245016600055210006900221260000800290300001100298490000800309520073100317653002201048653003001070653003801100653002101138653002001159100001701179700001801196700001801214856012501232       2021                        eng d  a2468-823100aRole of metal-support interaction for atmospheric pressure CO2 hydrogenation over Pd/(Ti)-SBA-15 catalyst: effect of titanium composition on products selectivity0 aRole of metalsupport interaction for atmospheric pressure CO2 hy  cJUL  a1117320 v5113 aThe potential role of metal-support interaction for tuning the product selectivity during atmospheric pressure CO2 hydrogenation has been demonstrated on Pd/(Ti)-SBA-15 catalyst. Highly dispersed Pd NPs on SBA-15 (Pd/ SBA-15) was synthesized and further modified with titanium of varying composition. Comparison of catalytic activity of Pd/Ti-SBA-15 with its counterparts (Pd/SBA-15 and Pd/TiO2) illustrated the significance of strong PdTi interface in this catalyst and its role in tuning the product selectivity of CO2 hydrogenation. The generation of an ample amount of oxygen vacancies in the Pd/Ti-SBA-15 catalyst with maximum metallic Pd sites in close vicinity of Ti is proposed to boost the CO2 hydrogenation activity.10aCO2 hydrogenation10aMetal-support interaction10aModified deposition precipitation10aoxygen vacancies10aTitanosilicates1 aSoni, Yogita1 aGupta, Sharad1 aVinod, C., P.  uhttp://library.ncl.res.in/content/role-metal-support-interaction-atmospheric-pressure-co2-hydrogenation-over-pdti-sba-15