02375nas a2200217   4500008004100000022001400041245010500055210006900160260000900229300001400238490000700252520160400259100002901863700002001892700002601912700002001938700002201958700002401980700003002004856012302034       2023                        eng d  a2052-412900aDonor strapped perylene bisimide macrocycle and its lemniscate dimer with extended charge separation0 aDonor strapped perylene bisimide macrocycle and its lemniscate d  cOCT   a5099-51070 v103 a<p>
	Macrocyclic structures are fascinating due to their unique design and capability to place chromophores in specific orientations, resulting in exciting optoelectronic properties. However, the synthetic challenges limit the broad exploration of such systems. Herein, we report a thiophene-diacetylene-based ring strapped perylene bisimide macrocycle and its notably different electron transfer features. Single-crystal analysis of the macrocycle pointed to the nearly orthogonal placement of donor-acceptor units, facilitating better electronic communication between them. Interestingly, introduction of an alkyl substituent on the peripheral thiophene ring opened the possibility of forming a higher oligomer macrocycle consisting of two strapped perylene bisimide units. Diffusion and two-dimensional NMR experiments provided insight into the structure of the figure-eight-shaped lemniscate dimer. Transient absorption measurements showed faster electron transfer and extended stabilization of the charge-separated state. The thiophene-diacetylene-based ring is a better donor unit to facilitate rapid electron transfer and extended charge separation in the macrocycle and its lemniscate dimer. The new macrocycle design enables the formation of higher analogs equally capable of stabilizing the charge-separated state. Donor-acceptor (D-A) macrocycle designs position the respective units to achieve ultrafast electron transfer precisely and an extended charge-separated state. Here, we report a D-A macrocycle and its lemniscate dimer molecule with exciting electron transfer features.</p>
1 aVeer, Sairam, Dnyaneshwa1 aGoswami, Tanmay1 aRavindranathan, Sapna1 aGonnade, Rajesh1 aKharbanda, Nitika1 aGhosh, Hirendra, N.1 aBabu, Sukumaran, Santhosh  uhttp://library.ncl.res.in/content/donor-strapped-perylene-bisimide-macrocycle-and-its-lemniscate-dimer-extended-charge