01272nas a2200169 4500008004100000022001400041245022200055210006900277260011000346300001400456520041200470100002400882700002500906700002300931700001800954856013000972 2005 eng d a1359-734500aConcomitant dimorphs of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates with different halogen bonding contacts: first order crystal-to-crystal thermal phase transition of kinetic form to the thermodynamic form0 aConcomitant dimorphs of triOphalobenzoylmyoinositol 135orthoform aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcOCT a5870-58723 a
Crystallization of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates from ethyl acetate-petroleum ether solution produced concomitant dimorphs that have different halogen bonding contacts; the kinetic form with C-(BrO)-O-...-C contacts upon heating to 185 degrees C, converts completely to the thermodynamic form with C-(BrOLC)-O-... contacts via crystal-to-crystal first order phase transition.
1 aGonnade, Rajesh, G.1 aBhadbhade, Mohan, M.1 aShashidhar, M., S.1 aSanki, A., K. uhttp://library.ncl.res.in/content/concomitant-dimorphs-tri-o-p-halobenzoyl-myo-inositol-135-orthoformates-different-halogen-1