01695nas a2200205 4500008004100000022001400041245013500055210006900190260006800259300001200327490000700339520088800346653002101234653003401255653002101289653001401310100002001324700001901344856012601363 2005 eng d a0021-899500aFunctional copolymers of p-cumyl phenyl methacrylate and glycidyl methacrylate: synthesis, characterization, and reactivity ratios0 aFunctional copolymers of pcumyl phenyl methacrylate and glycidyl a111 RIVER ST, HOBOKEN, NJ 07030 USAbJOHN WILEY & SONS INCcJUL a336-3470 v973 a
Free-radical polymerization of p-cumyl phenyl methacrylate (CPMA) was performed in benzene using bezoyl peroxide as an initiator at 80° C. The effect of time on the molecular weight was studied. Functional copolymers of CPMA and glycidyl methacrylate (GMA) with different feed ratios were synthesized by free-radical polymerization in methyl ethyl ketone at 70° C, and they were characterized by FTIR and H-1-NMR spectroscopy. The molecular weights and polydispersity indexes of the polymers and copolymers were determined by gel permeation chromatography. The copolymer composition was determined by H-1-NMR. The glass-transition temperature of the polymer and the copolymers was determined by differential scanning calorimetry. The reactivity ratios of the monomers were determined by the Fineman-Ross and Kelen-Tudos methods. © 2005 Wiley Periodicals, Inc.
10acopolymerization10afunctionalization of polymers10aglass-transition10asynthesis1 aRatnaprabha, K.1 aDaliya, P., K. uhttp://library.ncl.res.in/content/functional-copolymers-p-cumyl-phenyl-methacrylate-and-glycidyl-methacrylate-synthesis-0