01094nas a2200229 4500008004100000022001400041245009500055210006900150260008600219300001200305490000700317520027800324653001300602653001400615653000900629653002200638653002000660100002000680700002700700700001900727856011800746 2008 eng d a0039-791100aDimethyl sulfoxide pivaloyl chloride: a new reagent for oxidation of alcohols to carbonyls0 aDimethyl sulfoxide pivaloyl chloride a new reagent for oxidation a325 CHESTNUT ST, SUITE 800, PHILADELPHIA, PA 19106 USAbTAYLOR & FRANCIS INCcFEB a746-7530 v383 a
An efficient procedure for conversion of alcohols to the corresponding carbonyl compounds, an alternative to the classical Swern oxidation, is described. Pivaloyl chloride is employed as a mild and inexpensive electrophile. A possible reaction mechanism is proposed.
10aAlcohols10acarbonyls10aDMSO10apivaloyl chloride10aSwern oxidation1 aDubey, Abhishek1 aKandula, Subba, Rao V.1 aKumar, Pradeep uhttp://library.ncl.res.in/content/dimethyl-sulfoxide-pivaloyl-chloride-new-reagent-oxidation-alcohols-carbonyls-0