01892nas a2200241 4500008004100000022001400041245011500055210006900170260009900239300001400338490000700352520094900359653003801308653002401346653002001370653001401390653001801404100003101422700002101453700002401474700002501498856012701523 2010 eng d a0266-353800aExfoliation of clay layers in polypropylene matrix using potassium succinate-g-polypropylene as compatibilizer0 aExfoliation of clay layers in polypropylene matrix using potassi aTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLANDbELSEVIER SCI LTDcSEP a1550-15560 v703 a
The efficiency of potassium succinate-g-polypropylene (KPPSA) as compatibilizer for the dispersion of clay in a high molecular weight polypropylene during melt mixing for the preparation of nanocomposites was evaluated and compared with maleic anhydride-g-polypropylene (PPMA). Nanocomposites were prepared by direct melt mixing and by masterbatch methods and the structure obtained was characterized by WAXD and TEM. The exfoliation and better dispersion of the organoclay was observed with KPPSA than PPMA. The dispersion of clay was found to be dependent on the method of preparation, type and the amount of compatibilizer used. The dispersion was better when the nanocomposites were prepared by two step masterbatch route than the single step direct mixing method. Flexural moduli and crystallization behavior were studied and correlated with the dispersion of organoclay in the PP matrix. (C) 2010 Elsevier Ltd. All rights reserved.
10adifferential scanning calorimetry10aMechanical property10aNano composites10aNanoclays10apolypropylene1 aRama, Mallikarjuna, Shroff1 aNeppalli, Ramesh1 aChellaswamy, Ramesh1 aSwaminathan, Sivaram uhttp://library.ncl.res.in/content/exfoliation-clay-layers-polypropylene-matrix-using-potassium-succinate-g-polypropylene-0