01505nas a2200205 4500008004100000022001400041245009700055210006900152260010700221300001400328490000700342520070200349653001801051653001301069653003101082653002401113100001901137700002201156856012101178 2012 eng d a0970-707700aKinetics of hydrogenation of lauric acid in a batch slurry reactor using Ru-Sn/TiO2 catalyst0 aKinetics of hydrogenation of lauric acid in a batch slurry react a11/100 RAJENDRA NAGAR, SECTOR 3,, SAHIBABAD 201 005, GHAZIABAD, INDIAbASIAN JOURNAL OF CHEMISTRYcJUN a2767-27710 v243 a
Ru-Sn catalyst was prepared in-house by impregnation method. This catalyst was found to be stable for four recycles. The rate of hydrogenation of lauric acid (LAC) using Ru-Sn/TiO2 catalyst was found to be linearly dependent on catalyst loading, lauric acid concentration old hydrogen partial pressure. The rate data obtained from kinetic study were fitted to simple rate equation based on Langmuir-Hinshelwood (L-H) type model. Based on kinetic data the hydrogenation of lauric acid over Ru-Sn/TiO2 catalyst is proposed to occur by I dual site mechanism the activation energy for hydrogenation of lauric acid to lauryl alcohol (LAOH) using Rii-Sn/TiO2 catalyst was found to be 77.2 kJ/mol.
10aHydrogenation10akinetics10aLangmuir-Hinshelwood model10aRu-Sn/TiO2 catalyst1 aShinde, S., B.1 aDeshpande, R., M. uhttp://library.ncl.res.in/content/kinetics-hydrogenation-lauric-acid-batch-slurry-reactor-using-ru-sntio2-catalyst-0