01277nas a2200229 4500008004100000022001400041245009600055210006900151260007600220300001000296490000700306520039100313653002000704653002400724653005200748653002700800653004100827100001900868700001700887700002100904856012200925 2013 eng d a0009-429300aAlpha-trimethylsilylmethylamine radical cation in the synthesis of cyclic amines and beyond0 aAlphatrimethylsilylmethylamine radical cation in the synthesis o aSCHWARZTORSTRASSE 9, CH-3007 BERN, SWITZERLANDbSWISS CHEMICAL SOCcFEB a30-380 v673 a
The evolution of chemistry associated with the photoinduced electron transfer (PET)-generated alpha-trimethylsilylmethylamine radical cation cyclization to a tethered olefin to synthesize byclic amine structural frame works is presented in chronological order. The importance of this interesting chemistry is demonstrated by the synthesis of several novel glycosidase inhibitors.
10a1-N-Iminosugars10aalpha-Amine radical10aalpha-Trimethylsilyl methylamine radical cation10aGlycosidase inhibitors10aPhotoinduced electron transfer (PET)1 aPandey, Ganesh1 aDey, Debasis1 aGadre, Smita, R. uhttp://library.ncl.res.in/content/alpha-trimethylsilylmethylamine-radical-cation-synthesis-cyclic-amines-and-beyond-0