01277nas a2200193 4500008004100000022001400041245009900055210006900154260011000223300001200333490000600345520049100351100003100842700002000873700001900893700002000912700002400932856012700956 2015 eng d a2041-652000aFe(III) phytate metallogel as a prototype anhydrous, intermediate temperature proton conductor0 aFeIII phytate metallogel as a prototype anhydrous intermediate t aTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLANDbROYAL SOC CHEMISTRYcOCT a603-6070 v63 a
A proton conducting metallogel [FNPA; ferric nitrate (FN)-phytic acid (PA)] is synthesized by immobilizing a protogenic ligand (phytic acid) using iron(III) nitrate in DMF. The xerogel shows high proton conductivity of 2.4 x 10(-2) S cm(-1) at 120 degrees C, the best value known among all metal organic materials (MOMs). Marking the first such attempt in MOMs, an electrode made using the xerogel showed a power density of 0.94 mW cm(-2) at 0.6 V under dry fuel cell conditions.
1 aAiyappa, Harshitha, Barike1 aSaha, Subhadeep1 aWadge, Pritish1 aBanerjee, Rahul1 aKurungot, Sreekumar uhttp://library.ncl.res.in/content/feiii-phytate-metallogel-prototype-anhydrous-intermediate-temperature-proton-conductor-0