@article {17}, title = {Interfacial deposition of Ag on Au seeds leading to AucoreAgshell in organic media}, journal = {Journal of Colloid and Interface Science}, volume = {312}, number = {16}, year = {2007}, month = {AUG}, pages = {498-505}, publisher = {ACADEMIC PRESS INC ELSEVIER SCIENCE}, type = {Article}, address = {525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA}, keywords = {core-shell nanoparticles, Gold, HRTEM, interfacial seeded growth, Silver, XPS}, issn = {0021-9797}, doi = {10.1016/j.jcis.2007.03.032}, author = {Chandran, S. Prathap and Ghatak, J. and Satyam, P. V. and Sastry, Murall} } @article {17}, title = {Short synthesis of (+)-harzialactone A and (R)-(+)-4-hexanolide via proline-catalyzed sequential alpha-aminooxylation and horner-wadsworth-emmons olefination of aldehydes}, journal = {Tetrahedron-Asymmetry}, volume = {18}, number = {16}, year = {2007}, month = {AUG}, pages = {1795-1798}, publisher = {PERGAMON-ELSEVIER SCIENCE LTD}, type = {Article}, address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}, abstract = {

{In melts, ring polymers assume more compact conformations compared to linear chains with the same degree of polymerization N-r, i.e. R-r similar to N-r(nu) with nu approximate to 0.4, where R-r is the radius of gyration. Upon gradually substituting some of the ring polymers with linear chains, the ring molecules swell. In the limit of infinite dilution, their size scales as R-r similar to N-r(0.5). We present a scaling argument based on the blob model to capture this transition. Ring-linear blends are modeled as a semidilute solution of ring polymers in a theta-solvent consisting of linear chains. The model predicts that the size of the ring polymer remains unchanged up to the overlap concentration c(r)(*

}, keywords = {core-shell nanoparticles, Gold, HRTEM, interfacial seeded growth, Silver, XPS}, issn = {0957-4166}, doi = {10.1016/j.tetasy.2007.07.031}, author = {Kotkar, Shriram P. and Suryavanshi, Gurunath S. and Sudalai, Arumugarn} } @article { ISI:000298175400132, title = {Novel synthesis of nano-calcium carbonate (CaCO3)/polystyrene (PS) core-shell nanoparticles by atomized microemulsion technique and its effect on properties of polypropylene (PP) composites}, journal = {Polymers for Advanced Technologies}, volume = {22}, number = {12}, year = {2011}, month = {DEC}, pages = {2571-2582}, publisher = {WILEY-BLACKWELL}, address = {111 RIVER ST, HOBOKEN 07030-5774, NJ USA}, abstract = {

Calcium carbonate (CaCO3)/polystyrene (PS) nanoparticles (\< 100 nm) with core-shell structure were synthesized by atomized microemulsion technique. The polymer chains were anchored onto the surface of nano-CaCO3 through triethoxyvinyl silane (TEVS) as a coupling agent. Ammonium persulfate (APS), sodium dodecyl sulfate (SDS) and n-pentanol were used as initiator, surfactant, and cosurfactant, respectively. Polymerization mechanism of core-shell latex particles was discussed. Encapsulation of nano-CaCO3 by PS was confirmed by using transmission electron microscope (TEM). Grafting percentage of core-shell particles was investigated by Thermogravimetric Analyzer (TGA). Nano-CaCO3/PS core-shell particles were characterized by Fourier transform infrared (FTIR) spectrophotometer and differential scanning calorimeter (DSC). The results of FTIR revealed existence of a strong interaction at the interface of nano-CaCO3 particle and PS, which implies that the polymer chains were successfully grafted onto the surface of nano-CaCO3 particle through the link of the coupling agent. In addition, TGA and DSC results indicated an enhancement of thermal stability of core-shell materials compared with the pure nano-PS. Nano-CaCO3/PS particles were blended with polypropylene (PP) matrix on Brabender Plastograph by melt process with different wt\% of loading (i.e. 0.1-1 wt\%). The interfacial adhesion between nano-CaCO3 particles and PP matrix was significantly improved when the nano-CaCO3 particles were grafted with PS, which led to increased thermal, rheological, and mechanical properties of (nano-CaCO3/PS)/PP composites. Scanning electron microscope (SEM) and atomic force microscope (AFM) images showed a perfect dispersion of the nano-CaCO3 particles in PP matrix. Copyright (C) 2011 John Wiley \& Sons, Ltd.

}, keywords = {atomized microemulsion, core-shell nanoparticles, mechanical properties, polypropylene (PP), Rheological properties, Thermal properties}, issn = {1042-7147}, doi = {10.1002/pat.1802}, author = {Mishra, Satyendra and Chatterjee, Aniruddha and Singh, RajPal} } @article {46002, title = {Stealth emulsion based on natural rubber latex, core-shell ferrofluid/carbon black in the S and X bands}, journal = {Nanotechnology}, volume = {30}, year = {2019}, month = {AUG }, pages = {315703}, type = {Article}, abstract = {

A lossy dielectric with an appropriate magnetic property is one of the requirements of a stealth material. The thickness of the absorber and the corresponding bandwidth of absorption are also other deciding factors that determine the choice of the material as microwave absorbers. A stable emulsion, which is lossy as well as magnetic, is promising, since it can be coated on surfaces with required thickness in the desired band. A magnetic nanofluidic emulsion serves the purpose. A microwave absorbing emulsion based on natural rubber latex with core-shell magnetic nanoparticles, based on superparamagnetic iron oxide nanoparticles (SPIONs), was developed. The effect of additives like carbon black on the bandwidth of absorption was also studied as a function of weight percentage of carbon black. The complex dielectric permittivity and magnetic permeability were evaluated using a vector network analyser in the S and X bands. Furthermore, these results were modelled using surface impedance equations. These investigations revealed that the incorporation of carbon black enhances the bandwidth of absorption and an emulsion with the required dielectric permittivity and magnetic permeability can be tailored for stealth applications.

}, keywords = {carbon black, core-shell nanoparticles, ferrofluid, microwave absorbing paint, natural rubber latex}, issn = {0957-4484}, doi = {10.1088/1361-6528/ab1194}, author = {Vinayasree, S. and Nair, Ajalesh Balachandran and Mani, Manoj and Archana, V. N. and Joseph, Rani and Mohanan, P. and Joy, P. A. and Anantharaman, M. R.} }