@article { ISI:000233927900004,
	title = {Influence of hydrothermal pretreatment on acidity and activity of H-GaAlMFI zeolite for the propane aromatization reaction},
	journal = {Microporous and Mesoporous Materials},
	volume = {87},
	number = {1},
	year = {2005},
	month = {DEC},
	pages = {23-32},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>The acidity and propane aromatization activity of H-GaAlMFI has been investigated subsequent to different hydrothermal (HT) pretreatments. Extensive degalliation of framework Ga occurred during the HT pretreatments; the framework Si/Ga ratio nearly doubled when the steam concentration was increased from 0\% to 80\%. The extent of degalliation and corresponding loss of strong zeolitic acidity (measured in terms of pyridine chemisorbed at 400 degrees C) was particularly severe at high (\&gt; 500 degrees C) temperatures and steam concentrations (\&gt; 40 mol\%). Framework Al in the GaAlMFI zeolite was found to be very stable; the FW Si/Al ratio did not change to any appreciable extent even after severe HT pretreatments. Each of the HT pretreatment parameters (concentration of steam: 0-80\%, HT temperature: 400-600 degrees C and length of HT pretreatment: 0-6 h) showed a profound influence on the propane aromatization activity. The product selectivity was, however, only mildly affected by the HT pretreatments. The following factors were found to be important for high propane aromatization activity (a) strong zeolitic acidity and (b) optimal content/dispersion of the extra-framework Ga species which are formed in situ during the HT pretreatments. (c) 2005 Elsevier Inc. All rights reserved.</p>},
	keywords = {Acidity, aromatic distribution, Ga-based zeolites, hydrothermal treatment and steam, propane aromatization},
	issn = {1387-1811},
	doi = {10.1016/j.micromeso.2005.07.028},
	author = {Choudhary, Tushar V. and Kinage, A. and Banerjee, S. and Choudhary, Vasant R.}
}
@article { ISI:000226717900001,
	title = {Influence of PdO content and pathway of its formation on methane combustion activity},
	journal = {Catalysis Communications},
	volume = {6},
	number = {2},
	year = {2005},
	month = {FEB},
	pages = {97-100},
	publisher = {ELSEVIER SCIENCE BV},
	type = {Article},
	address = {PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS},
	abstract = {<p>The methane oxidation reaction is known to induce changes in the surface structure and composition of Pd catalysts; making it extremely arduous to relate the methane oxidation activity to specific catalyst properties by conventional methods (continuous flow reactor studies). To circumvent this, methodical pulse reactor studies have been undertaken to obtain correlations between the initial methane combustion activity and the catalyst properties (Pd-0/PdO content and path of PdO formation). While the initial methane combustion activity (at 160-280 degreesC) continuously increased with increasing PdO concentration (0-100\%) in the catalyst, it continuously decreased with increasing Pddegrees content (0-100\%). Controlled studies were undertaken to obtain catalysts with identical PdO content by two pathways: (i) by controlled partial oxidization of Pd-0/Al2O3 and (ii) by controlled partial reduction of PdO/Al2O3. Interestingly, for a given PdO content, the catalysts obtained by partial oxidation of Pd-0/Al2O3 showed a significantly superior performance to the catalyst obtained by partial reduction of PdO/Al2O3 for all the temperatures investigated. These studies unambiguously show that along with the relative concentration of PdO, the PdO formation pathway is also critical in deciding the methane combustion activity of the catalyst. (C) 2004 Elsevier B.V. All rights reserved.</p>},
	keywords = {Methane combustion, Oxidation, partially oxidized Pd-0/Al2O3, partially reduced PdO/Al2O3, Pd-0/Al2O3, PdO/Al2O3, pulse reaction of methane},
	issn = {1566-7367},
	doi = {10.1016/j.catcom.2004.11.004},
	author = {Choudhary, Tushar V. and Banerjee, S. and Choudhary, Vasant R.}
}
