@article {43627,
	title = {Cu-Catalyzed iminative hydroolefination of unactivated alkynes en route to 4-imino-tetrahydropyridines and 4-aminopyridines},
	journal = {Chemical Communications},
	volume = {52},
	year = {2016},
	month = {OCT},
	pages = {13475-13478},
	abstract = {A general method for synthesizing 4-imino tetrahydropyridine derivatives is achieved, from readily available beta-enaminones and sulfonyl azides, which comprises a sequential copper catalyzed ketenimine formation and its hitherto inaccessible intramolecular hydrovinylation. The products are shown as ready precursors for highly valuable 4-sulfonamidopyridine derivatives via DDQ mediated oxidation.},
	doi = {10.1039/c6cc08081b},
	author = {Kumar, Ravi and Thorat, Shridhar H. and Reddy, Maddi Sridhar}
}
@article {49540,
	title = {Charge transfer effect on relaxation mechanism in hydrated pyrrole-water systems following N-2s ionization},
	journal = {ChemPhysChem},
	volume = {26},
	year = {2025},
	month = {APR},
	type = {Article},
	abstract = {<p>
	This study investigates the relaxation mechanisms of pyrrole and pyrrole-water clusters (C4H5N-(H2O)n, where n=0-3 \${n = 0 - 3}\$ ) following N-2s ionization of pyrrole. Using various theoretical methods, we focus on the influence of water molecules and charge transfer on these non-radiative relaxation pathways. Our simulations included pyrrole solvated in 494 explicit water molecules equilibrated at 300 K and also employed a polarizable continuum model (PCM) to make the system more realistic and gain additional insights. In hydrated environments, the hydrogen bonding network between pyrrole and surrounding water molecules facilitates enhanced non-radiative relaxation pathways following inner valence ionization. Since these are hydrogen bonding systems, we have explored the possibility of proton transfer, which could occur in conjunction with other electronic decay processes.</p>
},
	keywords = {ab initio-calculations, auger decay, charge transfer, proton transfer, pyrrole},
	issn = {1439-4235},
	doi = {10.1002/cphc.202400962},
	author = {Kumar, Ravi and Bhattacharjee, Kankana and Ghosh, Aryya and Vaval, Nayana}
}
