@article { ISI:000346161500008,
	title = {Protecting-group-free diastereoselective total synthesis of (+/-)-6-epi-cleistenolide and chemoenzymatic synthesis of (-)-6-epi-cleistenolide},
	journal = {European Journal of Organic Chemistry},
	number = {36},
	year = {2014},
	month = {DEC},
	pages = {8049-8054},
	publisher = {WILEY-V C H VERLAG GMBH},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	abstract = {<p>A short, efficient, practical, and protecting-group-free diastereoselective total synthesis of (+/-)-6-epi-cleistenolide (1) has been achieved in five steps in 60\% overall yield. The use of a chemoenzymatic approach also gave (-)-6-epi-cleistenolide (1) (\&gt;99.9\% ee). The Achmatowicz reaction, chemoselective oxidation of a hemiacetal, diastereoselective 1,3-anti reduction of alpha-hydroxy ketone, and enzymatic resolution of a 1,3-diol are the key features of this linear total synthesis. The synthetic strategy demonstrated in this paper could be extended for an asymmetric total synthesis of (-)-cleistenolide (1) and related biologically active natural products.</p>},
	keywords = {Asymmetric synthesis, diastereoselectivity, Enzyme catalysis, Lipases, Oxygen heterocycles, Total synthesis},
	issn = {1434-193X},
	doi = {10.1002/ejoc.201403123},
	author = {Mahajan, Pankaj S. and Gonnade, Rajesh G. and Mhaske, Santosh B.}
}
@article {49351,
	title = {Asymmetric synthesis of inositol derivatives},
	journal = {Tetrahedron},
	volume = {162},
	year = {2024},
	month = {AUG},
	pages = {134113},
	type = {Article},
	abstract = {<p>
	Both the enantiomers of racemic 4- O -tosyl-6- O -benzyl- myo -inositol-1,3,5-orthoformate ( 2 ) were isolated by preferential crystallization and used to synthesize several enantiomeric myo -inositol derivatives - natural ononitol, natural laminitol, precursors for myo -inositol phosphates and an oxabicyclo [2.2.1] heptane derivative. This work demonstrates the potential of the enantiomeric tosylates D2 and L2 to serve as versatile starting materials for the absolute asymmetric synthesis of inositol derivatives and other natural products from symmetric myo -inositol since no optically active molecular entity was required for the resolution of 2.</p>
},
	keywords = {Asymmetric synthesis, Carbohydrate, Cyclitol, Inositol, Natural product},
	issn = {0040-4020},
	doi = {10.1016/j.tet.2024.134113},
	author = {Patil, Nivedita T. and Sarkar, Nitai and Mysore, S. Shashidhar and Gonnade, Rajesh G.}
}
