@article { ISI:000226290900011,
	title = {Rearrangement of allyl phenyl ether over Al-MCM-41},
	journal = {Journal of Catalysis},
	volume = {229},
	number = {1},
	year = {2005},
	month = {JAN},
	pages = {105-113},
	publisher = {ACADEMIC PRESS INC ELSEVIER SCIENCE},
	type = {Article},
	address = {525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA},
	abstract = {<p>Claisen rearrangement of allyl phenyl ether to o-allylphenol and a dihydrobenzofuran derivative was investigated over MCM-41 with different Si/Al ratios. Higher aluminum content, higher reaction temperatures, and longer run duration favor the formation of the ring compound 2,3-dihydro-2-methyl benzofuran. There is a close relationship between acidity and conversion, which suggests that the reaction occurs inside the large pores of MCM-41. The influence of temperature and catalyst Si/Al ratio on the reaction are examined by kinetic analysis, under the assumption of a first-order consecutive reaction. (C) 2004 Elsevier Inc. All rights reserved.</p>},
	keywords = {Al-MCM-41, allyl phenyl ether, Claisen rearrangement, Mesoporous material, molecular rearrangement, Solid acids},
	issn = {0021-9517},
	doi = {10.1016/j.jcat.2004.09.027},
	author = {Mathew, Nevin T. and Khaire, S. and Mayadevi, S. and Jha, Ratnesh Kumar and Sivasanker, S.}
}
@article { ISI:000309370500010,
	title = {Reactions in supercritical carbon dioxide},
	journal = {Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical \& Analytical Chemistry},
	volume = {51},
	number = {9-10, SI},
	year = {2012},
	month = {SEP},
	pages = {1298-1305},
	publisher = {NATL INST SCIENCE COMMUNICATION-NISCAIR},
	address = {DR K S KRISHNAN MARG, PUSA CAMPUS, NEW DELHI 110 012, INDIA},
	abstract = {<p>Use of conventional organic solvents often leads to the formation of hazardous waste, the disposal of which is a matter of environmental concern. Carbon dioxide is considered to be a green reaction medium and a good replacement for conventional organic solvents as it is benign and leads to elimination/reduction of hazardous wastes. Use of CO2 at near/above critical conditions has several additional advantages as the reactions can be pressure-tuned to eliminate transport resistance, increase solvent power and heat capacity. Hence, there has been considerable interest in the use of supercritical carbon dioxide as either a replacement of conventional organic solvent or as a co-solvent in reactions. Herein, recent developmenst in this area during the last decade is reviewed, specifically in gas-liquid (organic hydrogenation, hydroformylation and oxidation) and liquid-liquid (carbon-carbon coupling, alkylation, acetylation, esterification) reactions.</p>},
	keywords = {Alkylation, Carbon dioxide, Hydroformylation, Hydrogenation, Oxidation, Supercritical carbon dioxide},
	issn = {0376-4710},
	author = {Mayadevi, S.}
}
