@article {47047,
	title = {Ru-catalyzed asymmetric transfer hydrogenation of alpha-acyl butyrolactone via dynamic kinetic resolution: asymmetric synthesis of bis-THF alcohol intermediate of darunavir},
	journal = {Tetrahedron Letters},
	volume = {66},
	year = {2021},
	month = {MAR },
	pages = {152831},
	type = {Article},
	abstract = {<p>The Ru-catalyzed enantio- and diastereoselective dynamic kinetic resolution of alpha-(benzyloxy/benzoyloxy)acyl-gamma-butyrolactones has been examined via transfer hydrogenation. Employing the in situ prepared (R,R)-Ru-FsDPEN catalyst, the transfer hydrogenation of using formic acid/triethylamine at rt gave the corresponding (S)-3-((S)-2-(benzyloxy/benzoyloxy)-1-hydroxyethyl)dihydrofuran-2(3H)-on e with good to excellent diastereo- and enantioselectivity. One of the resulting hydrogenation product prepared on gram scales was utilized for the synthesis of (3R,3aS,6aR)-hexahydrofuro[2,3-b]furan-3-ol (1), a key synthetic intermediate of various HIV protease inhibitors such as darunavir with excellent enantio-(95\% ee) and diastereoselectivities (dr 95:5). (C) 2021 Elsevier Ltd. All rights reserved.</p>
},
	keywords = {Bis-THF-OH intermediate, Darunavir, Dynamic kinetic resolution, Ru-catalysis, transfer hydrogenation},
	issn = {0040-4039},
	doi = {10.1016/j.tetlet.2021.152831},
	author = {More, V. Ganesh and Malekar, V. Pushpa and Kalshetti, Rupali G. and Shinde, Mahesh H. and Ramana, V. Chepuri}
}
@article {47657,
	title = {Synthesis of anisotropic rod-like gold nanostructures in organic media (vol 133, 106, 2021)},
	journal = {Journal of Chemical Sciences},
	volume = {133},
	year = {2021},
	month = {DEC},
	pages = {120},
	type = {Correction},
	issn = {0974-3626},
	doi = {10.1007/s12039-021-01992-5},
	author = {Prasad, V. Bhagavatula L. and Sivasankaran, Prathap Chandran and Patel, Pitambar and Malekar, V. Pushpa and Maya, V. K. and Ramana, V. Chepuri}
}
