@article {44184,
	title = {Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages},
	journal = {Chemical Communications},
	volume = {54},
	year = {2018},
	month = {FEB},
	pages = {1873-1876},
	type = {Article},
	abstract = {<p>Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantio-selective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(II) cages built from chiral tris(imido) phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, beta-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.</p>},
	issn = {1359-7345},
	doi = {10.1039/c8cc00207j},
	author = {Rajasekar, Prabhakaran and Pandey, Swechchha and Paithankar, Harshad and Chugh, Jeetender and Steiner, Alexander and Boomishankar, Ramamoorthy}
}
@article {46434,
	title = {Chiral separation of styrene oxides supported by enantiomeric tetrahedral neutral Pd(II) cages},
	journal = {Inorganic Chemistry},
	volume = {58},
	year = {2019},
	month = {NOV},
	pages = {15017-15020},
	type = {Article},
	abstract = {<p>The separation of enantiomers is of considerable importance in the preparation of the compounds of biological interests, catalysis, and drug development. Here, we report a novel enantioseparation of styrene epoxides (SOs) resolved in the presence of a pair of enantio-enriched tetrahedral cages. Chiral neutral cages of formula [(Pd3X*)(4)(C6O4Cl2)(6)] ([X*](3-) = RRR-or SSS-[PO(N(*CH(CH3)Ph)(3)](3)) are constructed from Pcl, building units supported by tris(imido)phosphate trianions and chloranilate linkers. These cages exhibit considerable enantioselective separation capabilities toward a series of styrene epoxides via a crystallization inclusion method. A highest enantiomeric excess (ee) value of up to 80\% is achieved for the (R)-4-fluorostyrene oxide.</p>
},
	issn = {0020-1669},
	doi = {10.1021/acs.inorgchem.9b02389},
	author = {Rajasekar, Prabhakaran and Pandey, Swechchha and Ferrara, Joseph D. and Del Campo, Mark and Le Magueres, Pierre and Boomishankar, Ramamoorthy}
}
