@article {43879,
	title = {Pd-catalyzed regioselective mono-arylation: quinazolinone as the inherent directing group for C(sp(2))-H activation},
	journal = {Journal of Organic Chemistry},
	volume = {82},
	year = {2017},
	month = {JUN},
	pages = {6366-6372},
	type = {Article},
	chapter = {6366-6372},
	abstract = {<p>The Pd-catalyzed quinazolinone-directed regioselective monoarylation of aromatic rings by C-H bond activation is developed. A broad substrate scope is demonstrated for both quinazolinone as well as diary-liodonium triflates. The use of a base was found to be crucial for this transformation, unlike for the known nitrogen-directed arylations. All of the novel quinazolinones of biological interest were synthesized by using the operationally simple Pd(II)-catalyzed arylation reaction.</p>},
	keywords = {Aromatic rings, catalysis, Chemical activation, Chemical reactions, Palladium compounds, Regioselectivity},
	issn = {0022-3263},
	doi = {10.1021/acs.joc.7b00948},
	author = {Garad, Dnyaneshwar N. and Viveki, Amol B. and Mhaske, Santosh B.}
}
@article {46966,
	title = {Para-selective copper-catalyzed C(sp(2))-H amidation/dimerization of anilides via a radical pathway},
	journal = {Chemical Communications},
	volume = {56},
	year = {2020},
	month = {FEB },
	pages = {1565-1568},
	type = {Article},
	abstract = {<p>Copper-catalyzed amidation/dimerization of anilides via regioselective C(sp(2))-H functionalization is achieved. The para-selective amidation is accomplished on the anilide aromatic ring via a radical pathway leading to C-N bond formation in the presence of ammonium persulfate as a radical source/oxidant for the copper catalyst. The developed protocol tolerates a wide range of anilide substrates. The regioselectivity is confirmed by single-crystal X-ray studies.</p>
},
	issn = {1359-7345},
	doi = {10.1039/c9cc09824k},
	author = {Viveki, Amol B. and Garad, Dnyaneshwar N. and Gonnade, Rajesh G. and Mhaske, Santosh B.}
}
