@article {47789, title = {Amphiphilic indoline-based unsymmetrical squaraine dyes for dye-sensitized solar cells: modulating the dye-TiO2/electrolyte interface for nonaqueous and aqueous electrolytes}, journal = {ACS Applied Energy Materials}, volume = {4}, year = {2021}, month = {NOV}, pages = {13932-13942}, type = {Article}, abstract = {A high molar extinction coefficient with sharp absorption properties from the range of visible to near-infrared regions makes squaraine dyes very attractive and potential chromophores for dye-sensitized solar cell (DSSC) applications. Here, we report a series of alkyl groups and glycolic chain [triethylene glycol (TEG)]-wrapped amphiphilic indoline-based unsymmetrical squaraine dyes, where the number of carbon atoms in the alkyl groups and TEG was systematically changed by incorporating the alkyl groups and TEG within the dye molecule for controlling the self-assembly of the dyes on the TiO2 surface and to improve the interfacial properties at the dye-TiO2/electrolyte interface. Due to the same skeletal characteristics, ASQ dyes showed similar photophysical and electrochemical properties in solution. Photovoltaic characterization of ASQ dyes was carried out in nonaqueous and aqueous electrolytes to evaluate the effect of alkyl groups and TEG on nonaqueous and aqueous DSSC device performances. VOC, JSC, and photovoltaic efficiencies were systematically enhanced by increasing the number of carbon atoms of alkyl groups into the dye molecules for nonaqueous DSSCs. Furthermore, addition of chenodeoxycholic acid (CDCA) decreased the charge recombination processes and resulted in enhanced efficiency, VOC, and JSC (enhanced incident photon-to-current conversion efficiency performance) compared to that without CDCA. The ASQ4 dye gave the highest nonaqueous DSSC efficiency of 6.39\%, a VOC of 711 mV, and a JSC of 12.18 mA/cm2 with 2 equiv of CDCA in the ASQ dye series. Furthermore, increased carbon atoms in the alkyl groups showed a detrimental effect on the aqueous DSSC efficiency due to the mismatch in the polarity at the dye-TiO2/electrolyte interface, being the reason for the decreased device efficiencies from ASQ2 to ASQ4 dyes. The ASQ2 dye gave the highest aqueous DSSC efficiency of 2.36\%, a VOC of 611 mV, and a JSC of 4.75 mA/cm2 without CDCA in the ASQ dye series.}, doi = {10.1021/acsaem.1c02733}, url = {https://doi.org/10.1021/acsaem.1c02733}, author = {Singh, Ambarish Kumar and Nithyanandhan, Jayaraj} }