@article { ISI:000363828500010, title = {Efficient organocatalytic route for asymmetric total synthesis of stagonolide F}, journal = {Tetrahedron Letters}, volume = {56}, number = {45}, year = {2015}, month = {NOV}, pages = {6207-6209}, publisher = {PERGAMON-ELSEVIER SCIENCE LTD}, address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}, abstract = {

A stereoselective total synthesis of Stagonolide F (98\% ee) is described employing asymmetric alpha-aminooxylation, Jorgensen{\textquoteright}s asymmetric epoxidation, Brown asymmetric allylation, Steglich esterification and ring closing metathesis as key steps. The use of organocatalytic alpha-aminooxylation and Jorgensen{\textquoteright}s asymmetric epoxidation of aldehydes for the introduction of chirality makes this approach more attractive. (C) 2015 Elsevier Ltd. All rights reserved.

}, keywords = {alpha-Aminooxylation, Jorgensens{\textquoteright}s asymmetric epoxidation, Macrolide, Ring-closing metathesis, Total synthesis}, issn = {0040-4039}, doi = {10.1016/j.tetlet.2015.09.082}, author = {Shelke, Anil M. and Suryavanshi, Gurunath} }